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The programme saw Charles and Christina Trevanion begin the second leg of their road trip in the city of Manchester, before making their way to auction in Birkenhead.
However, Charles made an unexpected mistake which ended up costing him.
Picking up a pistol, Charles said: “This is George IV. it’s a duelling-type pistol and it’s 188-years-old.
“You can see that because its handle here is just about to fall off. But…oops.”
As the pistol broke into pieces, Charles hastily looked around to see if he had been caught, adding: “It has fallen off actually!”
Hysterically laughing in the voiceover booth, Tim Wonnacott teased: “Silly boy!”
Charles continued: “Oh dear me. Well that’s just great, isn’t it? I might have to buy it now just regardless.
“It is pretty tired but the reason I like it is because it’s in its original condition.